The Cambridge Latin Course is compatible with the National Latin Exam. Students taught from this textbook series can be successful on the NLE!
Joe Davenport, a long-time consultant for the CLC and a member of the NLE's Writing Committee, has put together documents outlining how the different units and stages from the undated fifth addition align with the NLE syllabus for 2023-2024.
You may also want to take a look at the previous Alignment Chart until the revisions are complete.